Thermodynamic properties and homogeneity regions of Tl 6SCl 4 and Tl 5Se 2Cl

Guseinov G., Babanly D., Sadygov F., Babanlı M.

Inorganic Materials, vol.45, no.2, pp.129-134, 2009 (SCI-Expanded, Scopus) identifier

  • Nəşrin Növü: Article / Article
  • Cild: 45 Say: 2
  • Nəşr tarixi: 2009
  • Doi nömrəsi: 10.1134/s0020168509020046
  • jurnalın adı: Inorganic Materials
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Səhifə sayı: pp.129-134
  • Açıq Arxiv Kolleksiyası: Məqalə
  • Adres: Bəli

Qısa məlumat

In this activity system Tl-Tl 2X-X (X = S, Se)are studied using emf measurements of concentration chains relative thallic electrode. The solid phase diagrams of these systems are clarified, homogeneity areas of the compounds Tl 6SCl 4 and Tl 5Se 2Cl are determined. On the basis of emf measurement results, relative partial molar functions of thallium in alloys and standard integral thermodynamic functions (ΔG 0(298 K), ΔH 0 (298 K), ΔS 0 (298 K)) of the ternary compounds Tl 6SCl 4 and Tl 5Se 2 Cl and phases of variable composition based on the latter are calculated. © 2009 Pleiades Publishing, Ltd.