CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

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Maharramov A. M., Duruskari G. S., Mammadova G. Z., Khalilov A. N., Aslanova J. M., Cisterna J., ...daha çox

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, vol.64, no.2, pp.4441-4447, 2019 (SCI-Expanded)

• Nəşrin Növü: Article / Article
• Cild: 64 Say: 2
• Nəşr tarixi: 2019
• Doi nömrəsi: 10.4067/s0717-97072019000204441
• jurnalın adı: JOURNAL OF THE CHILEAN CHEMICAL SOCIETY
• Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Səhifə sayı: pp.4441-4447
• Adres: Yox

Qısa məlumat

In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H center dot center dot center dot Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H center dot center dot center dot F, H center dot center dot center dot pi and H center dot center dot center dot Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.