Phase equilibria and decomposition of solid solutions in the YbTe–SnTe–PbTe system

Aliev Z., Ibadova G., İMAMƏLİYEVA S., Yusibov Y. A., Babanlı M.

Inorganic Materials, vol.53, no.8, pp.797-803, 2017 (SCI-Expanded, Scopus) identifier

  • Nəşrin Növü: Article / Article
  • Cild: 53 Say: 8
  • Nəşr tarixi: 2017
  • Doi nömrəsi: 10.1134/s0020168517080015
  • jurnalın adı: Inorganic Materials
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Səhifə sayı: pp.797-803
  • Açar sözlər: phase diagram, solid solutions, spinodal decomposition, tin and lead tellurides, YbTe–SnTe–PbTe system, ytterbium telluride
  • Açıq Arxiv Kolleksiyası: Məqalə
  • Adres: Bəli

Qısa məlumat

Phase equilibria in the YbTe–SnTe–PbTe system have been studied using differential thermal analysis, X-ray diffraction, scanning electron microscopy, and emf measurements on YbTe concentration cells. We have mapped out a number of vertical sections, the 400-K isothermal section of the YbTe–SnTe–PbTe phase diagram, and projections of its liquidus and solidus surfaces. The results demonstrate that the system is characterized by the formation of a continuous series of high-temperature solid solutions with a cubic structure (NaCl type), which undergo decomposition below ~1050 K. At room temperature, the YbTe solubility in the Sn1–xPbxTe solid solution system is ~33–35 mol %, whereas the extent of the YbTe-based solid solution series does not exceed 3 mol %.