Thermodynamic properties of terbium tellurides

İMAMƏLİYEVA S., Babanly D. M., Zlomanov V. P., Taghiyev D. B., Babanlı M.

Kondensirovannye Sredy Mezhfaznye Granitsy, vol.22, no.4, pp.453-459, 2020 (Scopus) identifier identifier

  • Nəşrin Növü: Article / Article
  • Cild: 22 Say: 4
  • Nəşr tarixi: 2020
  • Doi nömrəsi: 10.17308/kcmf.2020.22/3116
  • jurnalın adı: Kondensirovannye Sredy Mezhfaznye Granitsy
  • Jurnalın baxıldığı indekslər: Scopus
  • Səhifə sayı: pp.453-459
  • Açar sözlər: Electromotive forces method, Terbium tellurides, Thermodynamic functions
  • Açıq Arxiv Kolleksiyası: Məqalə
  • Adres: Bəli

Qısa məlumat

The paper presents the results of a study of solid-phase equilibria in the Tb-Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined by combining the EMF measurements of both types in the 300-450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated.