Recent advances in the synthesis of trifluoromethyl ethers through the direct O-trifluoromethylation of alcohols


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Rzayev R., NİYAZOVA A., Hüseynov M., MUSAYEVA V., Razzaq H. M.

Chemical Review and Letters, vol.7, no.8, pp.742-753, 2024 (Scopus) identifier

  • Nəşrin Növü: Article / Article
  • Cild: 7 Say: 8
  • Nəşr tarixi: 2024
  • Doi nömrəsi: 10.22034/crl.2024.470142.1391
  • jurnalın adı: Chemical Review and Letters
  • Jurnalın baxıldığı indekslər: Scopus
  • Səhifə sayı: pp.742-753
  • Açar sözlər: alcohols, Organofluorine compounds, oxidative O-functionalization, trifluoromethyl ethers, trifluoromethylation
  • Adres: Bəli

Qısa məlumat

In this review, the pivotal achievements and recent advances on direct O-trifluoromethylation of alcohols reported up to 2024 are retrospectively considered and their potency for synthesis of useful trifluoromethyl ethers is demonstrated. The reported data are organized according to main types of catalytic systems (i.e., metal-catalyzed/mediated, electro-catalyzed, base-mediated, and catalyst-free O-trifluoromethylations).