Synthesis, crystal structure and Hirshfeld surface analysis of 5-oxo-N-phenyl-3-(thiophen-2-yl)- 2,3,4,5-tetrahydro-[1,10-biphenyl]-4-carboxamide

Aliyeva, Khatira; Hökelek, Tuncer; Khrustalev, Victor; Rzayev, Rövnəq; Bhattarai, Ajaya; Maharramov, Abel; Shikhaliyev, Namig

doi:10.1107/s205698902500057x

Synthesis, crystal structure and Hirshfeld surface analysis of 5-oxo-N-phenyl-3-(thiophen-2-yl)- 2,3,4,5-tetrahydro-[1,10-biphenyl]-4-carboxamide

istinad üçün kopyala

Aliyeva K. N., Hökelek T., Khrustalev V. N., Rzayev R., Bhattarai A., Maharramov A. M., ...daha çox

Acta Crystallographica Section E: Crystallographic Communications, vol.81, no.Pt 2, pp.177-182, 2025 (ESCI)

Nəşrin Növü: Article / Article
Cild: 81 Say: Pt 2
Nəşr tarixi: 2025
Doi nömrəsi: 10.1107/s205698902500057x
jurnalın adı: Acta Crystallographica Section E: Crystallographic Communications
Jurnalın baxıldığı indekslər: Emerging Sources Citation Index (ESCI), Scopus
Səhifə sayı: pp.177-182
Açar sözlər: biphenyl-4- carboxamide, carboxamide, crystal structure, hydrogen bond, thiophene disorder
Adres: Bəli

Qısa məlumat

The asymmetric unit of the title compound, C23H19NO2S, contains two molecules that differ in the conformation of the two carboxamide moieties. In the crystal, intermolecular N - H⋯O hydrogen bonds link the molecules into chains propagating parallel to the c-axis direction. Between the molecules, weak C - H⋯π(ring) interactions are present, whereas π-π interactions are not observed. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (47.6%), H⋯C/C⋯H (33.4%) and H⋯O/O⋯H (11.6%) interactions. Orientational disorder is observed for both thiophene rings.