Thermodynamic study of the Ag-As-Se and Ag-S-I systems using the EMF method with a solid Ag4RbI5 electrolyte

Babanlı M., Mashadieva L., Velieva G., İMAMƏLİYEVA S., Shykhyev Y.

Russian Journal of Electrochemistry, vol.45, no.4, pp.399-404, 2009 (SCI-Expanded, Scopus) identifier

  • Nəşrin Növü: Article / Abstract
  • Cild: 45 Say: 4
  • Nəşr tarixi: 2009
  • Doi nömrəsi: 10.1134/s1023193509040077
  • jurnalın adı: Russian Journal of Electrochemistry
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Səhifə sayı: pp.399-404
  • Açar sözlər: Ag4RbI5, EMF method, Silver selenoarsenites, Silver thioiodide, Solid electrolyte, Thermodynamic properties
  • Adres: Bəli

Qısa məlumat

The EMF method with a solid Ag4RbI5 superionic conductor was used to study the Ag-As-Se and Ag-S-I systems in the composition ranges of Ag2Se-As2Se3-Se and Ag 2S-AgI-S, accordingly. Their solid-phase equilibrium diagrams are constructed or specified. The existence of ternary AgAs3Se 5, AgAsSe2, Ag3AsSe3, Ag 7AsSe6, Ag3SI compounds is confirmed. The standard partial and integral thermodynamic formation functions and also standard entropies were calculated for these compounds for the first time. © 2009 Pleiades Publishing, Ltd.