Akademik Məlumat İdarəetmə Sistemi
UNEC Journal of Engineering and Applied Sciences, vol.2, no.1, pp.64-73, 2022 (Scopus)
Dichlorodiazabutadienes are compounds of interest to synthetics with theirs unique structure. Thus, the presence of a diaza group, heminal dichlorine atoms, a combined heterodiene system in the composition of the compound and good solubility in organic solvents led to their application as synthons suitable for organic synthesis. In previous studies, dichlorodiazadiene derivatives were synthesized on the basis of some N-substituted hydrazones of o-, m-and p-nitrobenzoic aldehydes and many non-covalent bonds (hydrogen, nitrogen-halogen, halogen-chalcogen, halogen-halogen, pnicogenic bonds and etc.) in the obtained compounds have been studied for their role in crystal formation. It was found that the nature of the functional groups and the position in the benzene ring had a significant effect on the crystal design. In this regard, dichlorodiazadienes were synthesized from the reaction of CCl4 with corresponding phenylhydrazones, synthesized from the reaction of o-and m-nitrobenzaldehyde with 3-halogenphenylhydrazines.