Thermodynamic study of Cu-Tl-Te system using EMF technique with Cu 4RbCl 3I 2 solid electrolyte

Babanly N., Salimov Z., Akhmedov M., Babanlı M.

Russian Journal of Electrochemistry, vol.48, no.1, pp.68-73, 2012 (SCI-Expanded, Scopus) identifier

  • Nəşrin Növü: Article / Article
  • Cild: 48 Say: 1
  • Nəşr tarixi: 2012
  • Doi nömrəsi: 10.1134/s1023193512010041
  • jurnalın adı: Russian Journal of Electrochemistry
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Səhifə sayı: pp.68-73
  • Açar sözlər: Cu-Tl-Te system, Cu 4RbCl 3I 2 solid electrolyte, Thermodynamic functions
  • Açıq Arxiv Kolleksiyası: Məqalə
  • Adres: Bəli

Qısa məlumat

The EMF method with a solid Cu +-conducting electrolyte of Cu 4RbCl 3I 2 was sued to study the Cu-Tl-Te system in the temperature range of 300-420 K. A diagram of solid-phase equilibriums of this system is constructed, partial molar functions of copper in alloys, standard thermodynamic functions of formation and standard entropies of CuTlTe 2, CuTl 4Te 3, Cu 2TlTe 2, Cu 3TlTe 2, Cu 9TlTe 5 triple compounds and CuxTl 5 - xTe 3 solid solutions (0 < x < 1) are calculated. The obtained results confirmed the assumption as to the possibility of using this modification for the EMF technique for thermodynamic studies of copper-containing triple systems, even if they contain a less noble component than copper. © Pleiades Publishing, Ltd., 2012.