Phase equilibrium and metastability of liquid benzene at high pressures

Azreg-Ainou M., Huseynov A., Ibrahimoglu B.

JOURNAL OF CHEMICAL PHYSICS, vol.124, no.20, 2006 (SCI-Expanded) identifier identifier identifier

  • Nəşrin Növü: Article / Article
  • Cild: 124 Say: 20
  • Nəşr tarixi: 2006
  • Doi nömrəsi: 10.1063/1.2198808
  • jurnalın adı: JOURNAL OF CHEMICAL PHYSICS
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Adres: Yox

Qısa məlumat

This work is mainly an investigation of some of the liquid-to-solid properties of pure benzene on a restricted domain of high pressures (20.6 <= P <= 102.9 MPa). Newly obtained equilibrium experimental data and recently developed analytical equation of state are exploited and compared with each other and with previous experimental data. Curves fitted to the pressure, volume discontinuity, and enthalpy change at liquid-to-solid equilibrium points are provided. Concerning the metastable liquid benzene, both experimental and theoretical data for the minimum nucleation temperatures (limits of liquid metastability) are provided and correlated to each other. (c) 2006 American Institute of Physics.