Phenazine-1,6-dicarboxamides: Redox-Responsive Molecular Switches

Yin J., Khalilov A. N., Muthupandi P., Ladd R., Birman V. B.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol.142, no.1, pp.60-63, 2020 (SCI-Expanded) identifier identifier identifier

  • Nəşrin Növü: Article / Article
  • Cild: 142 Say: 1
  • Nəşr tarixi: 2020
  • Doi nömrəsi: 10.1021/jacs.9b11160
  • jurnalın adı: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Applied Science & Technology Source, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Compendex, Computer & Applied Sciences, EMBASE, MEDLINE, DIALNET, Index Chemicus (IC)
  • Səhifə sayı: pp.60-63
  • Adres: Yox

Qısa məlumat

We introduce phenazine-1,6-dicarboxamides as redox-responsive molecular switches. The reduction of their phenazine core transforms them from hydrogen-bond acceptors into hydrogen-bond donors and thus forces the secondary amide substituents to turn around. The resulting conformational changes are envisioned to form the basis for butterfly coil foldamers undergoing reversible extension and contraction in response to changing their oxidation state.