Adsorption of acridine yellow G from aqueous solutions using functionalized graphene nanoplatelets/modified polybutadiene hybrid composite

Əliyeva S.

Journal of the Chinese Chemical Society, vol.67, no.11, pp.2071-2081, 2020 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 67 Issue: 11
  • Publication Date: 2020
  • Doi Number: 10.1002/jccs.202000162
  • Journal Name: Journal of the Chinese Chemical Society
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, CAB Abstracts, INSPEC
  • Page Numbers: pp.2071-2081
  • Keywords: acridine yellow G, adsorption, desorption, dye, isotherms, kinetics, thermodynamics, wastewater treatment
  • Open Archive Collection: Article
  • Azerbaijan State University of Economics (UNEC) Affiliated: No

Abstract

This paper presents an analysis of adsorption of acridine yellow G (AYG) from aqueous solutions through the use of functionalized grapheme nanoplatelets/modified polybutadiene hybrid composite (FGNPs/MPB). The adsorption of AYG onto FGNPs/MPB was investigated based on the AYG concentration, pH, contact time, temperature, and adsorbent dose. A maximum adsorption capacity was obtained at a pH of 7 (23.7 mg/g), an adsorbent dose of 1.0 g/L (20.8 mg/g), and an initial AYG concentration of 28.5 mg/L (16.9 mg/g). The value of qe of FGNPs/MPB increases with an increase in temperature from 293 to 323 K. Equilibrium isotherm data were analyzed using the Langmuir and Freundlich isotherm models. The Langmuir model best describes the adsorption processes of AYG, which showed that the monolayer adsorption capacity of FGNPs/MBP is 22.9 mg/g. The pseudofirst-order, pseudosecond-order, and intraparticle diffusion models were used to study the kinetics of the AYG adsorption onto FGNPs/MPB. The pseudosecond-order model better described kinetic data for the adsorption of AYG onto FGNPs/MPB. Thermodynamic parameters, such as the Gibbs free energy, enthalpy, and entropy, indicated that the AYG adsorption onto FGNPs/MPB was spontaneous feasible, and endothermic.