Reciprocal system 3Tl2S + Sb2Se3 3Tl 2Se + Sb2S3

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Jafarov Y., Mirzoeva A., Babanlı M.

Russian Journal of Inorganic Chemistry, vol.53, no.1, pp.146-152, 2008 (SCI-Expanded, Scopus)

• Nəşrin Növü: Article / Article
• Cild: 53 Say: 1
• Nəşr tarixi: 2008
• Doi nömrəsi: 10.1134/s003602360801021x
• jurnalın adı: Russian Journal of Inorganic Chemistry
• Jurnalın baxıldığı indekslər: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Səhifə sayı: pp.146-152
• Açıq Arxiv Kolleksiyası: Məqalə
• Adres: Bəli

Qısa məlumat

Phase equilibria in the reciprocal system 3Tl2S + Sb 2Se3 3Tl2Se + Sb2S3 are investigated by DTA, X-ray powder diffraction, and emf measurements. Some polythermal sections, the isothermal section of the phase diagram at 400K, and the liquidus-surface projection for this system are constructed. The types and coordinates of invariant and univariant equilibria are determined. It is shown that the system is non-diagonal. Broad regions of solid solutions are found on the basis of the binary compounds Tl2S and Tl2Se and along the boundary system Sb2S3-Sb2Se3 and the sections Tl3SbS3-Tl3SbSe3, TlSbS2-TlSbSe2, and TlSb3S5- TlSb3Se5 of the phase diagram. © 2008 Pleiades Publishing, Ltd.