SYNTHESIZE OF (E)-1-(4-HALOGENPHENYL)-2-(2,2-DİCHLORO-1-(4-FLUOROPHENYL)VİNYL)DIAZENES AND THEM X-RAY STRUCTURAL ANALYSIS
New Materials, Compounds and Applications, vol.4, no.2, pp.94-98, 2020 (Scopus)
- Publication Type: Article / Article
- Volume: 4 Issue: 2
- Publication Date: 2020
- Journal Name: New Materials, Compounds and Applications
- Journal Indexes: Scopus
- Page Numbers: pp.94-98
- Keywords: catalytic olefinization reaction, dichlorodiazadienes, non-covalent interactions
- Open Archive Collection: Article
- Azerbaijan State University of Economics (UNEC) Affiliated: Yes
Abstract
During last years, the experiments on the halogen-halogen non-covalent interactions which have a great role in synthesize, catalytic and crystal engineering are used widely. According to this, corresponding dichlorodiazenes have been synthesized in catalytic olefinization conditionon the basis of 4-fluoro benzoy aldehyde. F in aldehyde fragment and Cl and Br atoms in hydrazine fragment of synthesized dichlorodiazadienes have an important role in determination of halogen-halogen non-covalent interactions. Cl···Cl, Cl···Br non-covalent interactions have a role in making monocrystal of the title compound and these interactions are investigated by X-Ray Structural Analysis.