Facile and efficient stereospecific deamination of aziridines using task-specific silica immobilized organosilane-based nitrite ionic liquid

Valizadeh H., Vessally E.

Monatshefte fur Chemie, 2024 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Publication Date: 2024
  • Doi Number: 10.1007/s00706-024-03254-9
  • Journal Name: Monatshefte fur Chemie
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Keywords: Aziridine, Deamination, Nitrite-ionic liquid, Solvent-free
  • Azerbaijan State University of Economics (UNEC) Affiliated: No

Abstract

Various cis- and trans-aziridine derivatives were deaminated via the reaction with task-specific silica immobilized organosilane-based nitrite ionic liquid. Corresponding cis- or trans-alkenes were produced as stereospecific products in good-to-excellent yields. The advantages of this method include the one-pot procedure, operational simplicity, solvent-free, and very short reaction times. Simple handling of this nitrite anion source nanoparticles and thus lowering the risks and hazards of a chemical process can offer other important advantages. Graphical abstract: (Figure presented.)