Probabilistic model of structural phase transition in perovskites


Jabarov S. H., Aliyev R. T., Ismayilova N. A.

MODERN PHYSICS LETTERS B, vol.35, no.12, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 12
  • Publication Date: 2021
  • Doi Number: 10.1142/s0217984921502110
  • Journal Name: MODERN PHYSICS LETTERS B
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC, zbMATH
  • Azerbaijan State University of Economics (UNEC) Affiliated: No

Abstract

In this work, the crystal structures and phase transitions of compounds with perovskite structure were investigated. The classification of structural phase transitions in perovskites was carried out, the most common crystal structures and structural phase transitions were shown. A mathematical model was constructed, a theorem was given and proved for the probability of a possible transition. The formulas E(tau 1) = ((lambda beta)2 8 + lambda beta 2 + 1)E(xi 1) and D(tau 1) = ((lambda beta)4 96 + (lambda beta)3 12 -3(lambda beta)2 8 -lambda beta 2 )(E xi 1)2 + ((lambda beta)2 8 + lambda beta 2 + 1)D(xi 1) are given for the mathematical expectation and variance of random variable tau 1, which is the moment when the stochastic process X(t) deviation from the boundary [0, beta] interval for the first time. According to the mathematical model, one of the trajectories of random processes corresponding to the phase transitions that occur in perovskites is constructed.