Direct vicinal sulfonyloximation of alkenes: an efficient and straightforward approach towards the synthesis of α-sulfonyl ketoximes

Hossaini Z., Abdolmohammadi S., Saeed S. M., Alkhazali W. H., Taher W. m., Alwan M., ...More

RSC Advances, vol.15, no.22, pp.17174-17185, 2025 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Review
  • Volume: 15 Issue: 22
  • Publication Date: 2025
  • Doi Number: 10.1039/d5ra02712h
  • Journal Name: RSC Advances
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Biotechnology Research Abstracts, Chemical Abstracts Core, Compendex, Metadex, Directory of Open Access Journals
  • Page Numbers: pp.17174-17185
  • Open Archive Collection: Article
  • Azerbaijan State University of Economics (UNEC) Affiliated: No

Abstract

Direct vicinal sulfonylative difunctionalization of simple alkenes represents a powerful strategy for the rapid assembly of β-functionalized sulfones from simple starting materials. In this context, the direct sulfonyloximation of alkene substrates has recently received much attention from the chemical community owing to important applications of α-sulfonyl ketoxime products in organic synthesis. This review provides an overview of recent research on the titled reactions, with an emphasis on the reaction patterns and mechanisms. Literature has been surveyed until the end of 2024.